Shuttling as a Strategy to Control the Regiochemistry of Bis-Additions on Fullerene Derivatives
| Autor: | Marco Carini, Tatiana Da Ros, Maurizio Prato, Aurelio Mateo-Alonso |
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| Přispěvatelé: | Carini, Marco, DA ROS, Tatiana, Prato, Maurizio, Mateo Alonso, Aurelio |
| Rok vydání: | 2016 |
| Předmět: |
Atomic and Molecular Physics
and Optic Fullerene Rotaxane Stereochemistry bis-adducts 010402 general chemistry 01 natural sciences bis-adduct cycloaddition fullerenes rotaxanes selectivity Atomic and Molecular Physics and Optics Physical and Theoretical Chemistry Atomic and Molecular Physics rotaxane Reactivity (chemistry) Fullerene derivatives 010405 organic chemistry Chemistry fullerene Regioselectivity Combinatorial chemistry Cycloaddition 0104 chemical sciences and Optics Selectivity |
| Zdroj: | ChemPhysChem. 17:1823-1828 |
| ISSN: | 1439-4235 |
| DOI: | 10.1002/cphc.201501174 |
| Popis: | The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts. |
| Databáze: | OpenAIRE |
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