Electrocontrolled Swelling and Water Uptake of a Three-Dimensional Conducting Polypyrrole Hydrogel
Autor: | Jadielson Lucas da Silva Antonio, Tom Lindfors, Susana I. Córdoba de Torresi, Lajos Höfler |
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Rok vydání: | 2016 |
Předmět: |
Conductive polymer
Materials science ELETROQUÍMICA Infrared spectroscopy 02 engineering and technology Quartz crystal microbalance 010402 general chemistry 021001 nanoscience & nanotechnology Polypyrrole 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Chemical engineering chemistry Attenuated total reflection Polymer chemistry Self-healing hydrogels Electrochemistry medicine Swelling medicine.symptom 0210 nano-technology Spectroscopy |
Zdroj: | Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual) Universidade de São Paulo (USP) instacron:USP |
ISSN: | 2196-0216 |
DOI: | 10.1002/celc.201600397 |
Popis: | Polypyrrole 3D hydrosponges of tubular structure were synthesized and electrochemically characterized. The Fourier transform infrared attenuated total reflection (FTIR-ATR) spectroscopy technique was employed to study the water uptake of the hydrosponges under different conditions. This technique presents several advantages over conventional swelling measurements due to its specificity that allows analyzing the kinetics of water uptake at the molecular level. In combination with mathematical modeling, FTIR-ATR spectroscopy also enables the calculation of the water diffusion coefficients in the hydrogels. The experimental setup also allows electroswelling of the hydrosponges to be studied. The results presented herein are complementary to those obtained with the electrochemical quartz crystal microbalance with dissipation (EQCM-D) technique and make it possible to determine the actual role played by water in the ionic exchange occurring in conducting polymers during their redox processes. Whereas EQCM-D shows the whole mass change in the film provoked by injection/ejection of ions and solvent molecules, FTIR-ATR spectroscopy follows water flux only, which thus allows separation of the solvent contribution. |
Databáze: | OpenAIRE |
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