A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC
| Autor: | Erlend Aunan, Cesare Atzori, Alessandro Damin, Sigurd Øien-Ødegaard, Francesca Bonino, Alessia Airi, Silvia Bordiga |
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| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
MOF characterization Cerium MOF synthesis DFT Combinatorial chemistry Inorganic Chemistry chemistry.chemical_compound Dicarboxylic acid chemistry Acetylene IR spectroscopy Raman spectroscopy Thermolabile MOF IR spectroscopy Raman spectroscopy DFT Cerium MOF synthesis MOF characterization Linker Topology (chemistry) MOF |
| Zdroj: | Dalton Transactions. 49:12-16 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c9dt04112e |
| Popis: | The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker. |
| Databáze: | OpenAIRE |
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