Phosphonate-substituted zirconium oxo clusters
| Autor: | Matthias Czakler, Ulrich S. Schubert |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
Original Paper
Zirconium Chemistry(all) Trimethylsilyl Structure analysis chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Phosphonate 0104 chemical sciences 3. Good health chemistry.chemical_compound chemistry Phosphonate ligands Polymer chemistry Zirconium alkoxides 0210 nano-technology Structural motif |
| Zdroj: | Monatshefte Fur Chemie |
| ISSN: | 1434-4475 0026-9247 |
| DOI: | 10.1007/s00706-015-1519-3 |
| Popis: | The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. The basic structural motif are Zr3O(µ2-OR)3(OR)3 units which are connected in different ways. Graphical abstract |
| Databáze: | OpenAIRE |
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