Sterically Controlled Late‐Stage Functionalization of Bulky Phosphines
| Autor: | Hao Deng, Marco Bengsch, Nico Tchorz, Constanze N. Neumann |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemistry – A European Journal. 28 |
| ISSN: | 1521-3765 0947-6539 |
| DOI: | 10.1002/chem.202202074 |
| Popis: | The fine-tuning of metal-phosphine-catalyzed reactions relies largely on accessing ever more precisely tuned phosphine ligands by de-novo synthesis. Late-stage C-H functionalization and diversification of commercial phosphines offers rapid access to entire libraries of derivatives based on privileged scaffolds. But existing routes, relying on phosphorus-directed transformations, only yield functionalization of C |
| Databáze: | OpenAIRE |
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