Classical/Non-classical Polyoxometalate Hybrids
| Autor: | Natalya V. Izarova, Volkmar Heß, Beatrix Santiago-Schübel, Paul Kögerler, Sabine Willbold |
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| Rok vydání: | 2016 |
| Předmět: |
ESI mass spectrometry
tungsten 010405 organic chemistry Stereochemistry Chemistry Communication Polyoxometalates Organic Chemistry 77Se NMR General Chemistry palladium 010402 general chemistry 01 natural sciences Communications Catalysis 0104 chemical sciences Group (periodic table) ddc:540 Polyoxometalate Organic chemistry |
| Zdroj: | Chemistry-a European journal 22(45), 16052-16056 (2016). doi:10.1002/chem.201604238 Chemistry (Weinheim an Der Bergstrasse, Germany) |
| ISSN: | 0947-6539 |
| DOI: | 10.1002/chem.201604238 |
| Popis: | Two polyanions [SeI V 2PdII 4WVI 14O56H]11− and [SeI V 4PdII 4WVI 28O108H12]12− are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non‐classical (late transition‐metal based) polyoxometalate units are joined. Requiring no supporting groups, this co‐condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM‐PdII coordination complexes and the young subclass of polyoxopalladates. Solid‐state, solution, and gas‐phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies. |
| Databáze: | OpenAIRE |
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