A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation
| Autor: | Naween Dahal, Young Kyu Hwang, Simon M. Humphrey, Jiwoong Yoon, Ilich A. Ibarra, Jong San Chang, Lindsey N. Shear, Ana J. Nuñez |
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| Rok vydání: | 2011 |
| Předmět: |
Coordination polymer
Inorganic chemistry Metals and Alloys General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials 1-Hexene Hexane chemistry.chemical_compound Adsorption chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Surface modification Lewis acids and bases Triphenylphosphine Phosphine |
| Zdroj: | Chemical communications (Cambridge, England). 47(43) |
| ISSN: | 1364-548X |
| Popis: | PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature. |
| Databáze: | OpenAIRE |
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