Headgroups versus symmetry in congruent ion pairs: which one does the job in mesomorphic aryl guanidinium and aryl imidazolium sulphonates?
| Autor: | Martin Butschies, Stefan Tussetschläger, Johannes Christian Haenle, Sabine Laschat, Christof Schneck, Frank Giesselmann, Markus Mansueto |
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| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Liquid Crystals. 41:821-838 |
| ISSN: | 1366-5855 0267-8292 |
| DOI: | 10.1080/02678292.2014.885600 |
| Popis: | Ionic liquid crystals based on congruent ion pairs composed of mesogenic cations and anions of similar shape provide an attractive tool for the tuning of mesophase properties. Here, the effect of the number and symmetry of lipophilic side chains and the type of head group on the phase type and thermal mesophase properties was probed by the synthesis and investigation of two series of novel guanidinium and imidazolium sulphonates and compared with the corresponding iodides. Their mesomorphic properties were examined via differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. While derivatives bearing only one alkoxy chain in either cation or anion with up to three alkoxy chains in total within the ion pairs display smectic A mesophases, hexagonal columnar mesophases were observed for all other compounds with four or five alkoxy chains totally irrespective of the head group. However, with increasing steric bulk, i.e. with a total of six alkoxy chains, the symmetry of the aryl moiety in the anion as well as the type of head group becomes relevant, resulting in hexagonal columnar or plastic phases for guanidinium sulphonates with symmetrical anions, while those with unsymmetrical anions were non-mesomorphic. In contrast, the corresponding imidazolium sulphonates displayed cubic phases for the combinations of symmetrical cation/symmetrical anion and symmetrical cation/unsymmetrical anion. If both ions are unsymmetrically substituted, the imidazolium sulphonate displayed a hexagonal columnar phase. The results further demonstrate the utility of the congruent ion pairs for tailor-made ionic liquid crystals. |
| Databáze: | OpenAIRE |
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