Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones
| Autor: | Dongmei Fang, Guanglin Weng, Zhouyu Wang, Huan Yang, Changjiang Peng, Yuanyuan Zhang, Xiaomei Zhang |
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| Rok vydání: | 2019 |
| Předmět: |
Chemistry
Hydrosilylation General Chemical Engineering Enantioselective synthesis 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Medicinal chemistry 0104 chemical sciences Catalysis chemistry.chemical_compound Lewis acids and bases 0210 nano-technology Conjugate |
| Zdroj: | RSC Advances. 9:11627-11633 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c9ra01180c |
| Popis: | Enantioselective conjugate hydrosilylation of β,β-disubstituted α,β-unsaturated ketones was realized. In the presence of a chiral picolinamide-sulfonate Lewis base catalyst, the reactions provided various chiral ketones bearing a chiral center at the β-position in up to quantitative yields with moderate enantioselectivities. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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