Designing Colloidal Molecules with Microfluidics
| Autor: | Bingqing Shen, Florent Malloggi, Patrick Tabeling, Joshua Ricouvier |
|---|---|
| Přispěvatelé: | Gulliver (UMR 7083), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL), Laboratoire Interdisciplinaire sur l'Organisation Nanométrique et Supramoléculaire (LIONS), Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie (ex SIS2M) (NIMBE UMR 3685), Institut Rayonnement Matière de Saclay (IRAMIS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Rayonnement Matière de Saclay (IRAMIS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), The authors also thank French Ministry of Research, ESPCI, and CNRS for their support to this work, European Project: 664823,H2020,H2020-FETOPEN-2014-2015-RIA,Microflusa(2015), Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Work (thermodynamics)
Materials science General Chemical Engineering Microfluidics microfluidics General Physics and Astronomy Medicine (miscellaneous) Nanotechnology colloidal molecules 02 engineering and technology high throughput 010402 general chemistry 01 natural sciences Biochemistry Genetics and Molecular Biology (miscellaneous) building blocks Colloid self‐assembly Molecule General Materials Science Throughput (business) Coupling Full Paper General Engineering self-assembly [CHIM.MATE]Chemical Sciences/Material chemistry Full Papers 021001 nanoscience & nanotechnology 0104 chemical sciences Tetrahedron Self-assembly 0210 nano-technology |
| Zdroj: | Advanced Science Advanced Science, Wiley Open Access, 2016, 3, pp.1600012. ⟨10.1002/advs.201600012⟩ Advanced Science, 2016, 3, pp.1600012. ⟨10.1002/advs.201600012⟩ |
| ISSN: | 2198-3844 |
| DOI: | 10.1002/advs.201600012⟩ |
| Popis: | International audience; The creation of new colloidal materials involves the design of functional building blocks. Here, a microfl uidic method for designing building blocks one by one, at high throughput, with a broad range of shapes is introduced. The method exploits a coupling between hydrodynamic interactions and depletion forces that controls the confi gurational dynamics of droplet clusters traveling in microfl uidic channels. Droplet clusters can be solidifi ed in situ with UV. By varying the fl ow parameters, clusters are prescribed a given size, geometry, chemical and/or magnetic heterogeneities enabling local bonding. Compact structures (chains, triangles, diamonds, tetrahedrons,...) and non-compact structures, such as crosses and T, diffi cult to obtain with current techniques are produced. Size dispersions are small (2%) and throughputs are high (30 000 h −1). The work opens a new pathway, based on microfl uidics, for designing colloidal building blocks with a potential to enable the creation of new materials. |
| Databáze: | OpenAIRE |
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