Self-assembly of colloidal polymers from two-patch silica nanoparticles
| Autor: | Serge Ravaine, Weiya Li, Céline Hubert, Adeline Perro, Etienne Duguet, Bin Liu |
|---|---|
| Přispěvatelé: | Centre de Recherche Paul Pascal (CRPP), Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut des Sciences Moléculaires (ISM), Université Montesquieu - Bordeaux 4-Université Sciences et Technologies - Bordeaux 1-École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), ANR-15-CE09-0010,ENLARgER,Dilater le système atomique conventionnel à l'échelle colloïdale grâce à des particules préprogrammées pour une valence donnée(2015), ANR-10-IDEX-0003,IDEX BORDEAUX,Initiative d'excellence de l'Université de Bordeaux(2010) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
education Nanoparticle 02 engineering and technology 010402 general chemistry 01 natural sciences chemistry.chemical_compound Colloid Copolymer General Materials Science Electrical and Electronic Engineering health care economics and organizations chemistry.chemical_classification Colloidal polymers technology industry and agriculture Polymer Self-assembly [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Atomic and Molecular Physics and Optics 0104 chemical sciences Patchy chemistry Chemical engineering Polymerization Nanoparticles Polystyrene 0210 nano-technology Macromolecule |
| Zdroj: | Nano Research Nano Research, Springer, 2020, 13 (12), pp.3371-3376. ⟨10.1007/s12274-020-3024-1⟩ |
| ISSN: | 1998-0124 1998-0000 |
| DOI: | 10.1007/s12274-020-3024-1⟩ |
| Popis: | International audience; We report the formation of colloidal polymers consisting of disk-like silica nanoparticles (NPs) with polystyrene (PS) chains at the bottom of their two cavities assembled through reduction of the solvent quality for the PS chains and linked by hydrophobic associations. We show that this NPs assembly exhibits a two-stage process involving reaction-controlled polymerization and diffusion-controlled polymerization. Colloidal polymer networks are produced by the incorporation of three-patch NPs, which serve as branching points between the colloidal chains. By co-assembling preformed homopolymers composed of patchy NPs of different sizes or surface chemical groups, block copolymers are also achieved. This study provides insight into the process of self-assembly of two-patch NPs by precisely designing the components to generate colloidal analogues of linear macromolecular chains. |
| Databáze: | OpenAIRE |
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