An Imidazo[1,5-α]Pyridine-Based Fluorometric Chemodosimeter for the Highly Selective Detection of Hypochlorite in Aqueous Media
| Autor: | Cheal Kim, Dongju Yun, Suh Mi Hwang |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Sociology and Political Science
Aqueous medium 010405 organic chemistry Clinical Biochemistry Hypochlorite 010402 general chemistry Highly selective 01 natural sciences Biochemistry Fluorescence 0104 chemical sciences Clinical Psychology chemistry.chemical_compound chemistry Nmr titration Pyridine Spectroscopy Law Social Sciences (miscellaneous) Nuclear chemistry |
| Zdroj: | Journal of Fluorescence. 29:451-459 |
| ISSN: | 1573-4994 1053-0509 |
| DOI: | 10.1007/s10895-019-02355-7 |
| Popis: | A new fluorometric chemodosimeter 2-amino-3-(((E)-3-(1-phenylimidazo[1,5-α]pyridin-3-yl)benzylidene)amino)maleonitrile (BPI-MAL) has been designed and synthesized for sensing hypochlorite. BPI-MAL showed a selective turn-on fluorescence for ClO− through hypochlorite-promoted de-diaminomaleonitrile reaction. It also could detect ClO− in the presence of various competitive anions including reactive oxygen species. Interestingly, sensor BPI-MAL was successfully applied as a fluorescent test kit for ClO− determination. The sensing property and mechanism of BPI-MAL toward ClO− were studied by fluorescence and UV-vis spectroscopy, NMR titration and DFT calculations. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink