A Simple and Efficient Synthesis of an Acid-Labile Polyphosphoramidate by Organobase-Catalyzed Ring-Opening Polymerization and Transformation to Polyphosphoester Ionomers by Acid Treatment

Autor:	Hai Wang, Yuefei Shen, Kellie Seetho, Karen L. Wooley, Shiyi Zhang, Fuwu Zhang, Jiong Zou, John-Stephen Taylor, Andrew P. Dove
Rok vydání:	2013
Předmět:	Polymers and Plastics Organic Chemistry Phosphoramidate Ring-opening polymerization Article Inorganic Chemistry Hydrolysis chemistry.chemical_compound Monomer chemistry Polymerization Benzyl alcohol Polymer chemistry Materials Chemistry Thermal stability Ionomer
Zdroj:	Macromolecules. 46:5141-5149
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma400675m
Popis:	The direct synthesis of an acid-labile polyphosphoramidate by organobase-catalyzed ring-opening polymerization and an overall two-step preparation of polyphosphodiester ionomers (PPEI) by acid-assisted cleavage of the phosphoramidate bonds along the backbone of the polyphosphoramidate were developed in this study. The ultrafast organobase-catalyzed ring-opening polymerization of a cyclic phospholane methoxyethyl amidate monomer initiated by benzyl alcohol allowed for the preparation of well-defined polyphosphoramidates (PPA) with predictable molecular weights, narrow molecular weight distributions (PDI
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::432ac8d8c8686270b9bc4ce93a1d7088 https://doi.org/10.1021/ma400675m Zobrazit plný text záznamu