High-Performance Organic Photovoltaics Incorporating an Active Layer with a Few Nanometer-Thick Third-Component Layer on a Binary Blend Layer

Autor: Hao Cheng Wang, Chien Yao Juan, Yu Che Lin, Pei Cheng, Anisha Mohapatra, Yang Yang, Bin Chang, Kung-Hwa Wei, Chung Hao Chen, Chih-Wei Chu, Hao Wen Cheng
Rok vydání: 2021
Předmět:
Zdroj: Nano Letters. 21:2207-2215
ISSN: 1530-6992
1530-6984
Popis: In this paper, a universal approach toward constructing a new bilayer device architecture, a few-nanometer-thick third-component layer on a bulk-heterojunction (BHJ) binary blend layer, has been demonstrated in two different state-of-the-art organic photovoltaic (OPV) systems. Through a careful selection of a third component, the power conversion efficiency (PCE) of the device based on PM6/Y6/layered PTQ10 layered third-component structure was 16.8%, being higher than those of corresponding devices incorporating the PM6/Y6/PTQ10 BHJ ternary blend (16.1%) and the PM6/Y6 BHJ binary blend (15.5%). Also, the device featuring PM7/Y1-4F/layered PTQ10 layered third-component structure gave a PCE of 15.2%, which is higher than the PCEs of the devices incorporating the PM7/Y1-4F/PTQ10 BHJ ternary blend and the PM7/Y1-4F BHJ binary blend (14.2 and 14.0%, respectively). These enhancements in PCE based on layered third-component structure can be attributed to improvements in the charge separation and charge collection abilities. This simple concept of the layered third-component structure appears to have great promise for achieving high-performance OPVs.
Databáze: OpenAIRE