Gas-phase inorganic chemistry: laser spectroscopy of calcium and strontium monoborohydrides

Autor:	P. C. Keller, A. M. R. P. Bopegedera, C. R. Brazier, Peter F. Bernath, W. T. M. L. Fernando, L. C. O'Brien, R. A. Hailey, F. S. Pianalto
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Inorganic chemistry Boranes General Chemistry Biochemistry Catalysis BORO chemistry.chemical_compound Colloid and Surface Chemistry chemistry Vibronic spectroscopy Molecule Spectroscopy Hyperfine structure Inorganic compound Diborane
Zdroj:	Scopus-Elsevier
ISSN:	1520-5126 0002-7863
Popis:	The CaBH{sub 4} and SrBH{sub 4} free radicals were synthesized by the reaction of Ca or Sr vapor with diborane, B{sub 2}H{sub 6}. The {tilde A}{sup 2}A{sub 1}-{tilde X}{sup 2}A{sub 1} and {tilde B}{sup 2}E-X{sup 2}A{sub 1} electronic transitions were detected by laser-induced fluorescence. The spectra are consistent with tridentate molecular structures with three bridging hydrogens and C{sub 3v} symmetry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::43133325711cadc24a1fe373e3c21428 https://doi.org/10.1021/ja00178a008 Zobrazit plný text záznamu