Autor:	Jose M. Goicoechea, Andrew R. Jupp, Érica Neves de Faria
Rok vydání:	2021
Předmět:	Inorganic Chemistry chemistry.chemical_compound Primary (chemistry) Deprotonation chemistry Methylenediamine Phosphide Hydrazine Electrophile Ethylenediamine Medicinal chemistry
Zdroj:	Dalton Transactions. 50:6991-6996
ISSN:	1477-9234 1477-9226
Popis:	We describe the synthesis of N-functionalised phosphinecarboxamides obtained by reaction of the 2-phosphaethynolate anion (PCO-) with diamines, specifically hydrazine, methylenediamine and ethylenediamine, in the presence of acid. The resulting neutral compounds can be deprotonated to generate phosphide anions that, when further reacted with electrophiles, form secondary phosphines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::43034ccf16172d2fe2bcba3a553b287c https://doi.org/10.1039/d1dt01198g Zobrazit plný text záznamu