Structure of bis(imidazole)(5,10,15,20-tetraphenylporphinato)iron(III) bis(cis-1,2-dicyanoethylenedithiolato)cuprate(III) tetrakis(tetrahydrofuran) solvate
| Autor: | Barbara R. Serr, C. M. Elliott, O. P. Anderson, C. E. L. Headford |
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| Rok vydání: | 1990 |
| Předmět: |
chemistry.chemical_classification
Nitrile Metalloporphyrins Stereochemistry Molecular Conformation General Medicine Crystal structure Triclinic crystal system Medicinal chemistry General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound X-Ray Diffraction chemistry X-ray crystallography Organometallic Compounds Molecule Imidazole Inorganic compound Tetrahydrofuran |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 46:500-502 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270189010620 |
| Popis: | [Fe(C44H28N4)(C3H4N2)2][Cu(C4N2S2)2].-4C4H8O, Mr = 1437.1, triclinic, P1-, a = 10.012 (4), b = 11.604 (6), c = 15.802 (7) A, alpha = 71.42 (4), beta = 87.12 (3), gamma = 78.45 (4) degrees, V = 1704 (1) A3, Z = 1, Dx = 1.40 g cm-3, lambda(Mo K alpha) = 0.7107 A, mu = 6.9 cm-1, F(000) = 747, T = 143 K, R = 0.063 for 4935 unique observed reflections. Fe is six-coordinate, Fe--N(porphinato) (av.) = 1.99 (2), Fe--N(imidazole) = 1.981 (3) A; Cu--S (av.) = 2.172 (8) A. |
| Databáze: | OpenAIRE |
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