Rotational energy transfer kinetics of optically centrifuged CO molecules investigated through transient IR spectroscopy and master equation simulations

Autor:	Matthew R. Laskowski, Tara J. Michael, Hannah M. Ogden, Millard H. Alexander, Amy S. Mullin
Rok vydání:	2022
Předmět:	Physical and Theoretical Chemistry
Zdroj:	Faraday Discussions. 238:87-102
ISSN:	1364-5498 1359-6640
DOI:	10.1039/d2fd00068g
Popis:	Rotational energy transfer of optically centrifuged CO is investigated with high-resolution transient IR absorption probing and master equation modeling. Observed rates are smaller than simulated rates, highlighting the role of angular momentum in collisional relaxation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::42b80ec3b6d0633676d29d2c72938be2 https://doi.org/10.1039/d2fd00068g Zobrazit plný text záznamu