Thermophysical properties in medium temperature range of several thio and dithiocarbamates
| Autor: | Manuel Temprado, Archana R. Parameswar, Alexei V. Demchenko, James S. Chickos, Joel F. Liebman, María Victoria Roux |
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| Přispěvatelé: | Ministerio de Ciencia y Tecnología (España), Dirección General de Investigación Científica y Técnica, DGICT (España), National Institute of General Medical Sciences (US), Ministerio de Educación y Ciencia (España) |
| Rok vydání: | 2008 |
| Předmět: |
Heat capacity
Phase transition Fusion Chemistry Enthalpy of fusion Dithiocarbamates Thio Thiazolines Oxazolines Atmospheric temperature range Fusion enthalpy Condensed Matter Physics DSC Differential scanning calorimetry Thiocarbamates Oxazines Physical chemistry Organic chemistry Physical and Theoretical Chemistry Thermal analysis |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| ISSN: | 1572-8943 1388-6150 |
| DOI: | 10.1007/s10973-007-8345-8 |
| Popis: | The present study reports a DSC study of the thio-and dithiocarbamates: 3H-benzoxazole-2-thione (2-mercaptobenzoxazole), 3H-benzothiazole-2-thione (2-mercaptobenzothiazole), thiazolidine-2-thione (2-mercapto-2-thiazoline), oxazolidine-2-thione (2-mercapto-2-oxazoline) and tetrahydro-1,3-oxazine-2-thione (5,6-dihydro-4H-1,3-oxazine-2-thiol) in the temperature interval T=268 K and the melting temperatures. Temperatures, enthalpies and entropies of fusion are reported. No solid-solid phase transitions were observed for the compounds in the temperature interval studied. The heat capacity of the compounds as a function of temperature was measured. We acknowledge the Spanish MCyT/DGI under project BTQ2006-12745. A. V. D. thanks National Institutes of General Medical Sciences (GM077170) for financial support of this research. M. T. thanks MEC/SEUI, AP2002-0603, Spain for financial support. |
| Databáze: | OpenAIRE |
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