Why do silanes reduce electron-rich phosphine oxides faster than electron-poor phosphine oxides?
| Autor: | Elizabeth H. Krenske, Alicia M. Kirk, Christopher J. O'Brien |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Silanes 010405 organic chemistry Aryl Metals and Alloys General Chemistry Electron 010402 general chemistry 01 natural sciences Silane Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Alkyl Phosphine |
| Zdroj: | Chemical Communications. 56:1227-1230 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc08718d |
| Popis: | Organophosphine-mediated reactions that generate P[double bond, length as m-dash]O-bonded byproducts can be transformed into catalytic processes by reducing the R3P[double bond, length as m-dash]O byproduct back to PR3in situ with a silane. DFT calculations explain why the most readily reduced phosphine oxides are those incorporating electron-rich (e.g. alkyl) substituents rather than electron-deficient (e.g. aryl) substituents. |
| Databáze: | OpenAIRE |
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