Self-hydroxylation of perbenzoic acids at a nonheme iron(ii) center

Autor:	Wonwoo Nam, Jaehong Han, Jan Uwe Rohde, Mark B. Consugar, Na Young Oh, Mi Hee Lim, Jinheung Kim, Kwan Mook Kim, Lawrence Que, Mi Sook Seo, Mi Joo Park
Rok vydání:	2005
Předmět:	Models Molecular Iron chemistry.chemical_element Nanotechnology Heme Hydroxylation Ring (chemistry) Benzoates Medicinal chemistry Oxygen Catalysis chemistry.chemical_compound Materials Chemistry chemistry.chemical_classification Molecular Structure Ligand Metals and Alloys General Chemistry Nonheme iron Surfaces Coatings and Films Electronic Optical and Magnetic Materials Enzyme chemistry Aromatic hydroxylation Intramolecular force Ceramics and Composites Oxidation-Reduction
Zdroj:	Chemical Communications. :5644
ISSN:	1364-548X 1359-7345
DOI:	10.1039/b511302d
Popis:	Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)-salicylate complexes through an intramolecular oxo-transfer process.
Databáze:	OpenAIRE
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