Modular Approach for Diversity-Oriented Synthesis of β-Fluoroalkylated Arenes via Pd/Norbornene Cooperative Catalysis

Autor: Shuxin Chen, Xue Liu, Kaidian Li, Wenchao Yang, Jian Lin, Ri‐Yuan Tang, Hanhong Xu, Zhaodong Li
Rok vydání: 2022
Předmět:
Zdroj: Chemistry, an Asian journal. 17(23)
ISSN: 1861-471X
Popis: A novel approach towards the efficient assembly of β-fluoroalkylated arenes is presented here based on Pd/norbornene cooperative catalysis, which features an excellent functional group tolerance, as well as a broad ipso termination scope. The mild reaction conditions enabled the diversity-oriented synthesis (DOS) of the 13 and 14-membered fluorinated macrolactones which is extremely challenging otherwise. This new abstract could be used instead of our old version.
Databáze: OpenAIRE
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