Synthesis and Complexing Properties of Alkyl (3-Oxo-2,3-dihydrothiophen-2-ylidene)- and (4-Oxothiazolidin-5-ylidene)acetate Derivatives

Autor:	M. F. Kosterina, A. I. Matern, V. S. Berseneva, O. A. Kramarenko, Alexey V. Tkachev, Yu. Yu. Morzherin, Vasiliy A. Bakulev
Rok vydání:	2004
Předmět:	chemistry.chemical_classification Double bond Organic Chemistry SODIUM CATION chemistry.chemical_element General Medicine Zinc Thiophene derivatives Medicinal chemistry Diethyl acetylenedicarboxylate Acetic acid chemistry.chemical_compound Membrane chemistry Organic chemistry Alkyl
Zdroj:	Russian Journal of Organic Chemistry. 40:866-869
ISSN:	1070-4280
Popis:	Condensation of dimethyl and diethyl acetylenedicarboxylate with thioacetamides gave the corresponding alkyl (3-oxo-2,3-dihydrothiophen-2-ylidene)- and (4-oxothiazolidin-5-ylidene)acetates. Treatment of these compounds with zinc in acetic acid resulted in reduction of the exocyclic double bonds. The products can be used in membrane processes as sodium cation carriers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::41f42fa7a453b4b63d197b0976935a2f https://doi.org/10.1023/b:rujo.0000044550.62124.94 Zobrazit plný text záznamu Plný text ve formátu PDF