A Highly Accurate and Analytic Equation of State for a Hard Sphere Fluid in Random Porous Media
| Autor: | W. Dong, M. F. Holovko |
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| Přispěvatelé: | Institute for Condensed Matter Physics of NAS of Ukraine (ICMP), National Academy of Sciences of Ukraine (NASU), Laboratoire de Chimie - UMR5182 (LC), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon)-Institut de Chimie du CNRS (INC) |
| Rok vydání: | 2009 |
| Předmět: |
Physics
Equation of state 010304 chemical physics High Energy Physics::Lattice Empirical correction Complex system 02 engineering and technology State (functional analysis) 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Analytic equation [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Simple (abstract algebra) 0103 physical sciences Materials Chemistry Particle Statistical physics Physical and Theoretical Chemistry 0210 nano-technology Porous medium ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Journal of Physical Chemistry B Journal of Physical Chemistry B, 2009, 113 (18), pp.6360-6365. ⟨10.1021/jp809706n⟩ Journal of Physical Chemistry B, American Chemical Society, 2009, 113 (18), pp.6360-6365. ⟨10.1021/jp809706n⟩ |
| ISSN: | 1520-5207 1520-6106 |
| DOI: | 10.1021/jp809706n |
| Popis: | An analytical equation of state (EOS) for a hard sphere fluid confined in random porous media is derived by extending the scaled particle theory to such complex systems with quenched disorders. A simple empirical correction allows us to obtain a highly accurate EOS with errors within the simulation ones. These are the first analytical results for non trivial off-lattice quench-annealed systems. |
| Databáze: | OpenAIRE |
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