Gram-Scale Synthesis of Cu(II)@COF via Solid-State Coordination Approach for Catalysis of Alkyne-Dihalomethane-Amine Coupling
| Autor: | Hua Qiao, Jian-Cheng Wang, Jin-Yan Shang, Jing-Lan Kan, Yu-Bin Dong, Xuan Kan |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Alkyne 010402 general chemistry Heterogeneous catalysis 01 natural sciences Coupling reaction 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Amine gas treating Chelation Physical and Theoretical Chemistry Acetonitrile Covalent organic framework |
| Zdroj: | Inorganic Chemistry. 60:3393-3400 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | A novel covalent organic framework material COF-DM, which contains chelating coordination environments, was synthesized at the gram level under mild conditions. In addition, its Cu(II)-loaded complex of Cu(II)@COF-DM was prepared by impregnating COF-DM in an acetonitrile solution of CuCl2 via a solid-state coordination approach. The obtained Cu(II)-loaded Cu(II)@COF-DM can be used as a highly active heterogeneous catalyst to catalyze the alkyne-dihalomethane-amine coupling reactions. |
| Databáze: | OpenAIRE |
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