Kinetics and mechanism of the oxidative regeneration of carbonyl compounds from phenylhydrazones by tetramminecopper(2+) bis (permanganate)

Autor: Raghvendra Shukla, László Kótai, Pradeep Sharma, Kalyan K. Banerji
Rok vydání: 2003
Předmět:
Zdroj: Journal of Chemical Research. 2003:184-185
ISSN: 1747-5198
DOI: 10.3184/030823403103173660
Popis: The oxidation of aldo- and keto-phenylhydrazones by tetraamminecopper(2+) bis(permanganate) (TACP), in aqueous acetic acid, proceeds through a mechanism involving the formation of a cyclic activated complex, in the rate-determining step.
Databáze: OpenAIRE