Retro-crosslinking of cluster-based hybrid polymers

Autor:	Franz René Kogler, Denise Silvia Dragan, Ulrich S. Schubert
Přispěvatelé:	Chemical Engineering and Chemistry
Jazyk:	angličtina
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Materials science Polymers and Plastics Acetylacetone Organic Chemistry Polymer Methacrylate Styrene chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Cluster (physics) Thermal stability Methyl methacrylate Chemical decomposition
Zdroj:	Polymer, 49(2), 378-385. Elsevier
ISSN:	0032-3861
DOI:	10.1016/j.polymer.2007.12.012
Popis:	Inorganic-organic hybrid polymers were prepared by co-polymerization of styrene or methyl methacrylate in the presence of small proportions of the cluster Zr4O2(methacrylate)12. The thermal properties of the hybrid polymers were improved by the cluster-crosslinking. Variation of the reaction conditions had little influence on the thermal properties, although the gelation times were clearly influenced. The cluster-crosslinks were completely and selectively degraded by means of acetylacetone. This allowed the unique possibility of determining the number average molecular weights and polydispersities of the organic polymers which were initially interconnected by the clusters. -© 2007 Elsevier Ltd. All rights reserved
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::41be9db74572279156bd01f570f96cb1 https://doi.org/10.1016/j.polymer.2007.12.012 Zobrazit plný text záznamu Full Text from ScienceDirect