An expedient reductive method for conversion of ketoximes to the corresponding carbonyl compounds

Autor:	Jason A. Witek, Steven M. Weinreb, Max M. Majireck
Rok vydání:	2010
Předmět:	Acetic acid chemistry.chemical_compound Aqueous solution Trimethylsilyl chloride chemistry Organic Chemistry Drug Discovery Organic chemistry Biochemistry Article Iron powder Catalysis
Zdroj:	Tetrahedron Letters. 51:3555-3557
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2010.04.131
Popis:	A wide array of readily prepared pivalates of ketoximes can be converted to the corresponding ketones in good yields by treatment with iron powder in THF containing catalytic amounts of both trimethylsilyl chloride and glacial acetic acid at room temperature for 30 minutes, followed by a brief aqueous workup.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::41be4609a74a15dcda8c98c19d34fd11 https://doi.org/10.1016/j.tetlet.2010.04.131 Zobrazit plný text záznamu Full Text from ScienceDirect