Crystal structure of a new polymeric thallium-lasalocid complex: lasalocide anion-thallium(I) containing aryl-Tl interactions

Autor:	T. Ben Hadda, Vickie McKee, F-Z. Khardli, Mostafa Mimouni, Mehmet Akkurt, S. Öztürk Yıldırım
Rok vydání:	2008
Předmět:	Ligand Aryl Organic Chemistry chemistry.chemical_element Crystal structure lcsh:QD241-441 chemistry.chemical_compound Crystallography Monomer lcsh:Organic chemistry chemistry Intramolecular force Thallium Carboxylate Lasalocid
Zdroj:	ARKIVOC, Vol 2008, Iss 15, Pp 121-132 (2008) Scopus-Elsevier
ISSN:	1551-7012
DOI:	10.3998/ark.5550190.0009.f13
Popis:	The title complex, [Tl(C34H53O8)](n), forms a pseudo individual monomer complex, in which the anionic oxygen of carboxylate group serves to neutralise the charge of Tl+, the other five O centres of the first lasalocid anionic ligand (Lasa 1) and in which this ligand is pentadentate O-ligand and bonded to a second Tl centre by using phenyl-metal coordination. A second lasalocid ligand (Lasa 2) is also pentadentate O-ligand and bridges the first Tl centre within the polymer. The monomeric unit is stabilized by strong intramolecular aryl-Tl type-metal half sandwich bonding interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::419c1ce0d982bd65a535a7b61f2b67a2 https://doi.org/10.3998/ark.5550190.0009.f13 Zobrazit plný text záznamu