Stereoselective aza-Darzens reactions of tert-butanesulfinimines: convenient access to chiral aziridines
| Autor: | Ian Churcher, Toni Moragas Solá, Robert A. Stockman, William Lewis |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Models Molecular Aldimine Molecular Structure Stereochemistry Organic Chemistry Aziridines Sulfonium Compounds Stereoisomerism Crystallography X-Ray Biochemistry Ethyl bromoacetate chemistry.chemical_compound chemistry Organic chemistry Stereoselectivity Imines Physical and Theoretical Chemistry |
| Zdroj: | Organicbiomolecular chemistry. 9(14) |
| ISSN: | 1477-0539 |
| Popis: | Stereoselective synthesis of 2,3-di- and 2,2′,3-tri-substituted aziridines in good yields and excellent diastereoselectivities are achieved through aza-Darzens reactions of a range of tert-butanesulfinyl aldimines and ketimines with ethyl bromoacetate. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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