Salts of the two-coordinate homoleptic manganese(i) dialkyl anion [Mn{C(SiMe3)3}2]− with quenched orbital magnetism

Autor:	Fernande Grandjean, Philip P. Power, Chun Yi Lin, Gary J. Long, Alasdair Formanuik, James C. Fettinger, Nicholas F. Chilton
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Magnetism Inorganic chemistry Metals and Alloys chemistry.chemical_element General Chemistry Manganese Crystal structure Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Crystallography chemistry.chemical_compound chemistry law X-ray crystallography Materials Chemistry Ceramics and Composites Homoleptic Ground state Electron paramagnetic resonance Crown ether
Zdroj:	Chemical Communications. 51:13275-13278
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c5cc05166e
Popis:	The structural and magnetic data for the Mn(i) dialkyl anionic salts [K2(18-crown-6)3][Mn{C(SiMe3)3}2]2 and [K(15-crown-5)2][Mn{C(SiMe3)3}2] are presented, indicating that these complexes possess a non-degenerate S = 2 ground state owing to 4s–3dz2 mixing upon reduction from the Mn(ii) parent complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::418d3645bc326867c74b58c37fe1a892 https://doi.org/10.1039/c5cc05166e Zobrazit plný text záznamu