Extraction of Cellulose Acetate from Cajuput (Melaleuca leucadendron) Twigs and Sugarcane (Saccharum officinarum) Bagasse by Environmentally Friendly Approach

Autor: Oktaviani Oktaviani, Eka Triwahyuni, Yanni Sudiyani, Atanu Kumar Das, Hafiizh Prasetia, Roni Maryana, Muryanto
Rok vydání: 2021
Předmět:
Zdroj: Waste and Biomass Valorization. 13:1535-1545
ISSN: 1877-265X
1877-2641
DOI: 10.1007/s12649-021-01610-y
Popis: This study was carried out to investigate the extraction of cellulose acetate (CA) from cajuput (Melaleuca leucadendron) twigs and sugarcane (Saccharum officinarum) bagasse using an environmentally friendly method. At first, cellulose was extracted from cajuput twigs (CT) and sugarcane bagasse (SB) through prehydrolysis followed by soda (NaOH) pulping and elemental chlorine-free (ECF) bleaching. Later, the extracted cellulose was acetylated using iodine (I) as a catalyst. The obtained CA was characterized by Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), scanning electron microscope (SEM) and X-ray diffraction. FTIR and NMR analysis proved the replacement of free OH (hydroxyl) groups by acetyl groups. The degree of substitution (DS) showed the acetylation capability of cellulose extracted from CT and SB as well. The diameter of CA and its crystallinity index (CrI) were measured by SEM and X-ray diffraction, respectively. The diameter of CA extracted from CT was approximately 10 μm and it was approximately 20 to 30 μm for SB. The CrI of the CA extracted from SB and CT was 75.6 and 60.2, respectively. Furthermore, the thermal gravimetric analysis showed that CA extracted from CT and SB was thermal resistance. Therefore, CT and SB will be potential alternative resources for CA production using the mentioned medthod.
Databáze: OpenAIRE
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