Recyclable, Strong Thermosets and Organogels via Paraformaldehyde Condensation with Diamines
| Autor: | Daniel J. Coady, James L. Hedrick, Hans W. Horn, Abdullah M. Alabdulrahman, Abdulmalik Bin-Taleb, Gavin O. Jones, Bryan D. McCloskey, Dylan J. Boday, Gijs M. ter Huurne, Jeannette M. Garcia, Hamid Al-Megren, Fares D. Alsewailem, Kumar Virwani |
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| Přispěvatelé: | Macromolecular and Organic Chemistry |
| Rok vydání: | 2014 |
| Předmět: |
chemistry.chemical_classification
Multidisciplinary Materials science Condensation polymer Environmental stress cracking Thermosetting polymer Polymer Carbon nanotube law.invention Solvent chemistry.chemical_compound chemistry Chemical engineering law Polymer chemistry Hemiaminal Polyhexahydrotriazine |
| Zdroj: | Science, 344(6185), 732-735. American Association for the Advancement of Science (AAAS) |
| ISSN: | 1095-9203 0036-8075 |
| Popis: | Recyclable Thermoset Polymers The high mechanical strength and durability of thermoset polymers are exploited in applications such as composite materials, where they form the matrix surrounding carbon fibers. The thermally driven polymerization reaction is usually irreversible, so it is difficult to recycle the constituent monomers and to remove and repair portions of a composite part. García et al. (p. 732 ; see the Perspective by Long ) now describe a family of polymers formed by condensation of paraformaldehyde with bisanilines that could form hard thermoset polymers or, when more oxygenated, produce self-healing gels. Strong acid digestion allowed recovery of the bisaniline monomers. |
| Databáze: | OpenAIRE |
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