Synthesis and reactivity of NHC-coordinated phosphinidene oxide

Autor:	Nicolas Chrysochos, U. Deva Priyakumar, Carola Schulzke, Ramapada Dolai, Hemant Kumar Rawat, Holger Braunschweig, Anukul Jana, Vadapalli Chandrasekhar, Ivo Krummenacher, Benedict J. Elvers, Pradeep Kumar Pal, Debabrata Dhara
Rok vydání:	2021
Předmět:	Pinacol Metals and Alloys Oxide General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Phosphinidene Polymer chemistry Materials Chemistry Ceramics and Composites Reactivity (chemistry) Carbene Stoichiometry
Zdroj:	Chemical communications (Cambridge, England). 57(75)
ISSN:	1364-548X
Popis:	Here we report the synthesis of an N-heterocyclic carbene (NHC)-stabilised phosphinidene oxide by the controlled oxygenation of a phosphinidene under ambient conditions. This compound can be further oxygenated to a phosphinidene dioxide. The stoichiometric reduction of a phosphinidene oxide with KC8 resembles the pinacol coupling reaction–the reduction of a carbonyl compound. We also looked at the stoichiometric oxidation of NHC-coordinated phosphinidene, phosphinidene oxide and phosphinidene dioxide with [NO][SbF6].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::410a3cdfe993c264db39f2ae4f9b0d05 https://pubmed.ncbi.nlm.nih.gov/34546278 Zobrazit plný text záznamu