Metal-free visible-light-promoted C(sp(3))–H functionalization of aliphatic cyclic ethers using trace O(2)

Autor: Ben Niu, Bryan G. Blackburn, Sébastien Laulhé, Maria Victoria Cooke, Krishnakumar Sachidanandan
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Green Chem
Popis: Presented is a light-promoted C–C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O(2) as sole green oxidant.
Databáze: OpenAIRE