Copper-catalyzed oxidative dehydrogenative functionalization of alkanes to allylic esters
| Autor: | Nicolaas P. van Leest, Rakesh Mondal, Nanda D. Paul, Kaj M. van Vliet, Bas de Bruin, Gargi Chakraborty |
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| Přispěvatelé: | Homogeneous and Supramolecular Catalysis (HIMS, FNWI) |
| Rok vydání: | 2020 |
| Předmět: |
Allylic rearrangement
010405 organic chemistry Chemistry Ligand Oxidative phosphorylation Annulene 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry Materials Chemistry Copper catalyzed Organic chemistry Surface modification Dehydrogenation Physical and Theoretical Chemistry |
| Zdroj: | Inorganica Chimica Acta, 500:119190. Elsevier |
| ISSN: | 0020-1693 |
| Popis: | Herein, we report a general, efficient and solvent-free method for the one-pot synthesis of allylic esters via dehydrogenation of unactivated alkanes and subsequent oxidative cross coupling with different substituted carboxylic acids. A simple, well defined and air stable Cu(II)-complex, [Cu(MeTAA)], featuring a tetraaza-macrocyclic ligand (tetramethyltetraaza[14]annulene (MeTAA)) is used as the catalyst. A wide variety of substituted allylic esters were synthesized in high yields starting from readily available starting materials. Control reactions were carried out to understand the reaction sequence and the plausible mechanism. |
| Databáze: | OpenAIRE |
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