Probing structure in submicronic aqueous assemblies of emulsified microemulsions and charged spherical colloids using SANS and cryo-TEM
| Autor: | Thibault Dégousée, Jéril Degrouard, Annie Brûlet, Anniina Salonen, François Muller |
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| Rok vydání: | 2015 |
| Předmět: |
Coalescence (physics)
endocrine system Materials science Aqueous solution digestive oral and skin physiology Cationic polymerization Nanotechnology Neutron scattering complex mixtures Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials Colloid Colloid and Surface Chemistry Pulmonary surfactant Chemical engineering Transmission electron microscopy Microemulsion |
| Zdroj: | Journal of Colloid and Interface Science. 446:114-121 |
| ISSN: | 0021-9797 |
| Popis: | The spatial distribution of charged spherical colloids when used as stabilizers of phytantriol-based emulsified microemulsions (EME, L2 symmetry group) is investigated. The coverage of the lipid-based mesophases by the colloids is monitored using small-angle neutron scattering (SANS) in contrast matching conditions and visualized using cryogenic transmission electron microscopy (cryo-TEM) imaging. The results demonstrate that, despite the stability of the emulsion droplets, very few colloids are ever found on the droplets. The stability of the EMEs is suggested to arise from the very slow ripening rates combined with punctual repulsion against coalescence from the isolated charged colloids on the bigger droplet surfaces. We show the possibility of creating a dense cover around the droplets by partially hydrophobizing the colloids by adsorbing a cationic surfactant on their surface. This opens up the possibilities for further modulation of the colloidal coverage in these systems. This is an interesting route for the design of new Colloid-ISAsome assemblies in which dense protective armors could be advantageous such as controlled delivery. |
| Databáze: | OpenAIRE |
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