Regioselective synthesis of bicyclic 1,3,5-triazepine system starting from tetrachloro-2-aza-1,3-butadienes
| Autor: | Julia A. Rusanova, Volodymyr Brovarets, Bohdan A. Demydchuk, Eduard B. Rusanov |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Annulation
Bicyclic molecule 010405 organic chemistry Stereochemistry Chemistry Regioselectivity General Chemistry 5-triazepine 010402 general chemistry 2cyclopentanediamine 01 natural sciences 0104 chemical sciences N-phenyl-1 Crystal lcsh:Chemistry chemistry.chemical_compound 3-butadienes lcsh:QD1-999 regioselective annulation Tetrachloro-2-aza-1 Cyclopentane |
| Zdroj: | Current Chemistry Letters, Vol 6, Iss 2, Pp 49-54 (2017) |
| ISSN: | 1927-7296 |
| Popis: | Readily available tetrachloro-2-aza-1,3-butadienes enter into directed cyclocondensation reaction with N-phenyl-1,2-cyclopentanediamine which leads to regioselective cyclopentane annulation by the 1,3,5-triazepine. The formation of the 1,3,5-triazepine derivatives was confirmed proved by 1H- and 13C-NMR spectral study, elemental analysis and, in one case, single-crystal x-ray crystallographic study. |
| Databáze: | OpenAIRE |
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