Lanthanide-doped luminescent ionogels
| Autor: | Kris Driesen, Jean Le Bideau, Luc Van Meervelt, Christiane Görller-Walrand, Peter Nockemann, Séverine Bellayer, Koen Binnemans, Kristof Van Hecke, André Vioux, Lydie Viau, Kyra Lunstroot |
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| Přispěvatelé: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Institut des Matériaux Jean Rouxel (IMN), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN) |
| Rok vydání: | 2008 |
| Předmět: |
Lanthanide
Coordination sphere Materials science Inorganic chemistry chemistry.chemical_element Terbium [CHIM.MATE]Chemical Sciences/Material chemistry 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Ionic liquid [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] Physical chemistry 0210 nano-technology Luminescence Europium Hybrid material ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Dalton Transactions Dalton Transactions, Royal Society of Chemistry, 2009, pp.298-306. ⟨10.1039/b812292j⟩ Dalton Transactions, Royal Society of Chemistry, 2009, pp.298. ⟨10.1039/b812292j⟩ |
| ISSN: | 1477-9226 1477-9234 |
| Popis: | International audience; Ionogels are solid oxide host networks con. ning at a meso-scale ionic liquids, and retaining their liquid nature. Ionogels were obtained by dissolving lanthanide(III) complexes in the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, [C(6)mim][Tf2N], followed by confinement of the lanthanide-doped ionic liquid mixtures in the pores of a nano-porous silica network. [C(6)mim][Ln(tta)(4)], where tta is 2-thenoyltrifluoroacetonate and Ln = Nd, Sm, Eu, Ho, Er, Yb, and [choline](3)[Tb(dpa)(3)], where dpa = pyridine-2,6-dicarboxylate (dipicolinate), were chosen as the lanthanide complexes. The ionogels are luminescent, ion-conductive inorganic-organic hybrid materials. Depending on the lanthanide(III) ion, emission in the visible or the near-infrared regions of the electromagnetic spectrum was observed. The work presented herein highlights that the confinement did not disturb the first coordination sphere of the lanthanide ions and also showed the excellent luminescence performance of the lanthanide tetrakis beta-diketonate complexes. The crystal structures of the complexes [C(6)mim][Yb(tta)(4)] and [choline](3)[Tb(dpa)(3)] are reported. |
| Databáze: | OpenAIRE |
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