N-Vinylpyridinium and -ammonium Tetrafluoroborate Salts: New Electrophilic Coupling Partners for Pd(0)-Catalyzed Suzuki Cross-Coupling Reactions
| Autor: | Neil J. Brown, Keith R. Buszek |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
Magnetic Resonance Spectroscopy
Vinyl Compounds Tetrafluoroborate Pyridinium Compounds Ligands Biochemistry Article Catalysis Coupling reaction chemistry.chemical_compound Suzuki reaction Polymer chemistry Organic chemistry Ammonium Physical and Theoretical Chemistry Chemistry Organic Chemistry Boronic Acids Quaternary Ammonium Compounds Coupling (electronics) Kinetics Solubility Electrophile Pyridinium Crystallization Palladium |
| Zdroj: | Organic Letters. 9:707-710 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/ol063027h |
| Popis: | N-Vinylpyridinium and -trialkylammonium tetrafluoroborate salts represent a new class of electrophilic coupling partner for Pd(0)-catalyzed Suzuki cross-coupling reactions and give very good to excellent yields of products with a wide range of boronic acids. The salts are easily prepared from activated acetylenes and pyridinium or trialkylammonium tetrafluoroborates to form crystalline, air-stable, and nonhygroscopic crystals. [reaction: see text]. |
| Databáze: | OpenAIRE |
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