Ternary synthesis of colloidal Zn3P2quantum dots

Autor:	Brandi M. Cossairt, Benjamin A. Glassy
Rok vydání:	2015
Předmět:	Condensed matter physics Chemistry Metals and Alloys Observable General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography Colloid Quantum dot Materials Chemistry Ceramics and Composites Zinc Cluster Ternary operation
Zdroj:	Chemical Communications. 51:5283-5286
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c4cc08068h
Popis:	The synthesis and characterization of crystalline colloidal zinc phosphide quantum dots with observable excitonic transitions ranging between 424-535 nm (2.3-2.9 eV) are reported. A ternary combination of ZnEt2, Zn(O2CR)2, and P(SiMe3)3, forms a pentanuclear zinc cluster on mixing followed by conversion to (Et2Zn)P(ZnO2CR)2(SiMe3) in a rate-determining step prior to quantum dot formation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4013c514564c4c00fb69830a357f0219 https://doi.org/10.1039/c4cc08068h Zobrazit plný text záznamu