Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts
| Autor: | Pasi Salonen, Ari Lehtonen, Anssi Peuronen |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
010402 general chemistry
01 natural sciences Redox vanadiini Catalysis Inorganic Chemistry Turn (biochemistry) chemistry.chemical_compound Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Catechol oxidase ta216 ta116 Catechol biology catalysis 010405 organic chemistry Ligand oxo transfer biomimetic 0104 chemical sciences chemistry katalyysi biology.protein vanadium Amine gas treating |
| Zdroj: | Inorganic Chemistry Communications. 86:165-167 |
| ISSN: | 1387-7003 |
| Popis: | Air-stable oxidovanadium(V) complexes with tetradentate amine bisphenolate ligands were made by the reaction of VOSO4·xH2O and ligand precursors in MeOH solutions. Isolated compounds were studied as catechol oxidase models as well as catalysts for epoxidation and sulfoxidation reactions. All compounds can catalyse such oxidation reactions without notable structure-activity correlations. The 51V NMR studies indicate that the complexes turn to the number of different species during the catalytic experiments. peerReviewed |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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