Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands

Autor:	Pingfan Wu, Bo Huang, Xiaokang Hu, Yongge Wei, Min Cheng, Zicheng Xiao, Xunliang Hu, Xinjun Lin
Rok vydání:	2017
Předmět:	Inorganic Chemistry Tris chemistry.chemical_compound chemistry 010405 organic chemistry Stereochemistry Surface modification 010402 general chemistry 01 natural sciences Combinatorial chemistry Derivative (chemistry) 0104 chemical sciences
Zdroj:	Dalton Transactions. 46:8505-8513
ISSN:	1477-9234 1477-9226
Popis:	A new synthetic approach to tri-substituted trisalkoxy-hexavanadate clusters containing different organic groups was developed in this work. Four mixed-valence or fully reduced POV hybrids were synthesized and structurally characterized, including an amino-containing derivative of hexavanadate, Na2[VIV3VV3O10{NH2C(CH2O)3}3] (1). Furthermore, a novel mixed-valence POV hybrid was prepared via the amidation of 1, indicating that 1 can be used as an excellent building block for the design and synthesis of mixed-valence POV functional materials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3f9aedddaeaa38b9ebee2c8e427ee385 https://doi.org/10.1039/c7dt01543g Zobrazit plný text záznamu