Rapid determination of carbendazim in complex matrices by electrospray ionization mass spectrometry with syringe filter needle
| Autor: | Wei Deng, Xiao Yang, Feng Wang, Ziyu Zhang, Ouping Huang, Yong Luo, Xiao-ju Wan, Yang Bicheng, Yun-jun Li, Xi-di Wan |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Analyte
Spectrometry Mass Electrospray Ionization Syringe filter Electrospray ionization 02 engineering and technology 01 natural sciences chemistry.chemical_compound Soil Limit of Detection Tandem Mass Spectrometry Humans Spectroscopy Syringe Chromatography High Pressure Liquid Detection limit Chromatography Pesticide residue Chemistry Carbendazim Syringes 010401 analytical chemistry Pesticide Residues Reproducibility of Results 021001 nanoscience & nanotechnology 0104 chemical sciences Fruit and Vegetable Juices Linear range Benzimidazoles Environmental Pollutants Carbamates 0210 nano-technology Water Pollutants Chemical |
| Zdroj: | Journal of mass spectrometry : JMS. 53(3) |
| ISSN: | 1096-9888 |
| Popis: | The determination of pesticide residues is an indispensable task in controlling food safety and environment protection. Carbendazim is one of the extensive uses of pesticides in the agricultural industry. In this study, a simple method utilizing syringe filter has been applied as electrospray ionization emitter for mass spectrometric identification and quantification of carbendazim in complex matrices including soil, natural water, and fruit juice samples, which contain many insoluble materials. With online syringe filter of the complex samples, most of insoluble materials such as soil were excluded in spray ionization process due to the filter effect, and analytes were subsequently sprayed out from syringe needle for mass spectrometric detection. The pore sizes of filters and diameters of syringe needles also were investigated. The analytical performances, including the linear range (1-200 ng·mL-1 ), limit of detection (0.2-0.6 ng·mL-1 , S/N > 3), limit of quantitation (3.5-8.6 ng·mL-1 , S/N > 10), reproducibility (6.4%-12.5%, n = 6), and recoveries (72.1%-91.0%, n = 6) were well acceptable for direct analysis of raw samples. Matrix effect for detection of carbendazim in soil samples also was experimentally investigated. This study demonstrated that syringe filter needle coupled with electrospray ionization mass spectrometry is a simple, efficient, and sensitive method for detection of pesticide residues in water, soil, and fruit juice for risk assessment. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text