From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal–Organic Frameworks
| Autor: | Laura Gagliardi, Isil Akpinar, Peng Li, Debmalya Ray, Timur Islamoglu, Omar K. Farha, Xuan Zhang, Marek B. Majewski, Christopher J. Cramer |
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| Rok vydání: | 2018 |
| Předmět: |
Lanthanide
Chemistry 02 engineering and technology Actinide 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal Transition metal visual_art visual_art.visual_art_medium Physical chemistry Metal-organic framework Physical and Theoretical Chemistry Isostructural 0210 nano-technology Electronic properties |
| Zdroj: | Inorganic Chemistry. 57:13246-13251 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes. |
| Databáze: | OpenAIRE |
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