Synthesis and catalytic applications of metal–organic frameworks: a review on recent literature
| Autor: | Manju Kurian, V. R. Remya |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Biomedical Engineering Pharmaceutical Science Medicine (miscellaneous) Nanochemistry Bioengineering Nanotechnology 02 engineering and technology 010402 general chemistry Heterogeneous catalysis 01 natural sciences Heterogeneous catalyst Catalysis lcsh:Chemistry lcsh:Technology (General) Thermal stability Porosity Flexibility (engineering) Metal–organic framework 021001 nanoscience & nanotechnology 0104 chemical sciences lcsh:QD1-999 Synthesis techniques lcsh:T1-995 Metal-organic framework 0210 nano-technology Porous medium Stability |
| Zdroj: | International Nano Letters, Vol 9, Iss 1, Pp 17-29 (2018) |
| ISSN: | 2228-5326 2008-9295 |
| DOI: | 10.1007/s40089-018-0255-1 |
| Popis: | Metal–organic frameworks (MOFs) are an emerging class of porous materials created by the assembly of inorganic connectors and organic linkers. They have potential applications in fields such as gas storage as well as separation, sensing, catalysis, and drug delivery due to its properties such as flexibility, porosity, high surface area and functionality. Among the various synthetic approaches for the preparation of MOFs, solvothermal and microwave-assisted methods are of particular importance, and hence have been used frequently. They have been recently used as heterogeneous catalysts in Friedel–Crafts reactions, condensations reactions, oxidations, coupling reactions, etc. However, owing to the low thermal stability and moisture sensitivity, their catalytic applications are limited. This short review covers recent developments in the synthetic methods employed for the preparation of MOFs as well as their catalytic applications. |
| Databáze: | OpenAIRE |
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