Electrocatalytic hydrogenation of benzoic acids in a proton-exchange membrane reactor

Autor:	Mahito Atobe, Yugo Shimizu, Atsushi Fukazawa, Naoki Shida
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Membrane reactor chemistry Organic Chemistry Inorganic chemistry Proton exchange membrane fuel cell High current Physical and Theoretical Chemistry Cyclohexanecarboxylic acid Electrochemistry Biochemistry Catalysis Alloy catalyst
Zdroj:	Organic & Biomolecular Chemistry. 19:7363-7368
ISSN:	1477-0539 1477-0520
DOI:	10.1039/d1ob01197a
Popis:	The highly efficient chemoselective electrocatalytic hydrogenation of benzoic acids (BAs) to cyclohexanecarboxylic acids (CCAs) was carried out in a proton-exchange membrane reactor under mild conditions without hydrogenation of the carboxyl group. Among the investigated catalysts, the PtRu alloy catalyst was found to be the most suitable for achieving high current efficiencies for production of CCAs. An electrochemical spillover mechanism on the PtRu alloy catalyst was also proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3f346e445d9cc29617a0aeaa66b2e007 https://doi.org/10.1039/d1ob01197a Zobrazit plný text záznamu