Palladium(0)-Catalyzed Intermolecular Allylic Dearomatization of Indoles by a Formal [4+2] Cycloaddition Reaction

Autor:	Run-Duo Gao, Qing-Long Xu, Yiting Gu, Li-Xin Dai, Shu-Li You, Bo Zhang
Rok vydání:	2016
Předmět:	Indole test Allylic rearrangement 010405 organic chemistry Chemistry organic chemicals Organic Chemistry Enantioselective synthesis food and beverages chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis Cycloaddition 0104 chemical sciences chemistry.chemical_compound Nucleophile Indoline Organic chemistry Palladium
Zdroj:	Chemistry - A European Journal. 22:11601-11604
ISSN:	0947-6539
Popis:	Bridged indoline derivatives were synthesized by an intermolecular Pd-catalyzed allylic dearomatization reaction of substituted indoles. The reaction between indoles and allyl carbonates bearing a nucleophilic alcohol side-chain proceeds in a cascade fashion, providing bridged indolines in excellent enantioselectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3e80b0fc2646008763e06abff701639a https://doi.org/10.1002/chem.201602691 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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