Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity

Autor:	Qiaomu Yang, Patrick J. Carroll, Yu-Heng Wang, Eric J. Schelter, Patrick J. Walsh, Yusen Qiao, Michael R. Gau
Rok vydání:	2021
Předmět:	Alkane chemistry.chemical_classification Cerium Multidisciplinary Chemistry Radical Photodissociation Alkoxy group Photocatalysis chemistry.chemical_element Reactivity (chemistry) Medicinal chemistry Adduct
Zdroj:	Science. 372:847-852
ISSN:	1095-9203 0036-8075
DOI:	10.1126/science.abd8408
Popis:	A complex role for chlorine radicals Radicals are atoms or molecules that are highly reactive because they have an unpaired electron. A common means of investigating whether they are involved in a particular reaction is to try to trap them with an acceptor compound. Yang et al. reinvestigated a photoinduced alkane oxidation reaction for which a trapping study had previously implicated alkoxy radicals. Their spectroscopic, kinetic, and isotopic labeling studies revealed that chlorine, rather than alkoxy, was the key radical intermediate; the prior trapping results had stemmed from its complexation with alcohols. Science , abd8408, this issue p. 847
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3dfa204820e14f6da8a73f398d859327 https://doi.org/10.1126/science.abd8408 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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