Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden–Popper phases
| Autor: | Jumi Bak, Hye-Sung Kim, Youngjae Hong, Yoon Heo, Sung-Yoon Chung, Hyung Bin Bae, Pilgyu Byeon |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Lanthanide
Multidisciplinary Materials science Science Chemical physics General Physics and Astronomy chemistry.chemical_element General Chemistry Crystal structure Electrostatics Oxygen General Biochemistry Genetics and Molecular Biology Article Tetragonal crystal system Crystallography Octahedron chemistry Distortion Structure of solids and liquids Inorganic chemistry Perovskite (structure) Materials for energy and catalysis |
| Zdroj: | Nature Communications Nature Communications, Vol 12, Iss 1, Pp 1-10 (2021) |
| ISSN: | 2041-1723 |
| Popis: | As the physical properties of ABX3 perovskite-based oxides strongly depend on the geometry of oxygen octahedra containing transition-metal cations, precise identification of the distortion, tilt, and rotation of the octahedra is an essential step toward understanding the structure–property correlation. Here we discover an important electrostatic origin responsible for remarkable Jahn–Teller-type tetragonal distortion of oxygen octahedra during atomic-level direct observation of two-dimensional [AX] interleaved shear faults in five different perovskite-type materials, SrTiO3, BaCeO3, LaCoO3, LaNiO3, and CsPbBr3. When the [AX] sublayer has a net charge, for example [LaO]+ in LaCoO3 and LaNiO3, substantial tetragonal elongation of oxygen octahedra at the fault plane is observed and this screens the strong repulsion between the consecutive [LaO]+ layers. Moreover, our findings on the distortion induced by local charge are identified to be a general structural feature in lanthanide-based An + 1BnX3n + 1-type Ruddlesden–Popper (RP) oxides with charged [LnO]+ (Ln = La, Pr, Nd, Eu, and Gd) sublayers, among more than 80 RP oxides and halides with high symmetry. The present study thus demonstrates that the local uneven electrostatics is a crucial factor significantly affecting the crystal structure of complex oxides. The authors observe two-dimensional shear faults in five different perovskite-type materials and detailed structures of more than 80 oxides and halides to elucidate an electrostatic origin for Jahn–Teller-type tetragonal distortion of oxygen octahedra. |
| Databáze: | OpenAIRE |
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